P Block — Easy JEE chemistry MCQ
**[JEE Mains 2026]** An element of p-block forms a species of type EH₄⁺, which when passed through a basic solution of K₂[HgI₄], forms a brown precipitate. Which element is E and what is the name of the test?
- A. N, Nessler's test
- B. P, phosphorus test
- C. S, Lassaigne's test
- D. C, carbon test
Solution
NH₄⁺ (ammonium ion) reacts with Nessler's reagent K₂[HgI₄] in basic medium to give a brown precipitate of iodide of Millon's base: [Hg₂N]I·H₂O.
This is a confirmatory test for ammonia/ammonium ions.
