Kinetics — Medium JEE chemistry MCQ
The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.
\textbf{List-I}
(P) Etard reaction
(Q) Gattermann reaction
(R) Gattermann-Koch reaction
(S) Rosenmund reduction
\textbf{List-II}
(1) Acetophenone $\stackrel{\mathrm{Zn}-\mathrm{Hg}, \mathrm{HCl}}{\longrightarrow}$
(2) Toluene $\underset{\text{(ii)}\mathrm{SOCl}_{2}}{\stackrel{\text { (i) } \mathrm{KMnO}_{4}, \mathrm{KOH}, \Delta}{\longrightarrow}}$
(3) Benzene $\underset{\text { anhyd. } \mathrm{AlCl}_{3}}{\stackrel{\mathrm{CH}_{3} \mathrm{Cl}}{\longrightarrow}}$
(4) Aniline $\underset{273-278 \mathrm{~K}}{\stackrel{\mathrm{NaNO}_{2} / \mathrm{HCl}}{\longrightarrow}}$
(5) Phenol $\stackrel{\mathrm{Zn}, \Delta}{\longrightarrow}$
- A. $\mathrm{P} \rightarrow 2$; $\mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 1 ; \mathrm{S} \rightarrow 3$
- B. $\mathrm{P} \rightarrow 1$; $\mathrm{Q} \rightarrow 3$; $\mathrm{R} \rightarrow 5$; $\mathrm{S} \rightarrow 2$
- C. $\mathrm{P} \rightarrow 3$; $\mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 1$; $\mathrm{S} \rightarrow 4$
- D. $\mathrm{P} \rightarrow 3$; $\mathrm{Q} \rightarrow 4$; R $\rightarrow 5$; $\mathrm{S} \rightarrow 2$
Solution
The correct option is **D**.