Kinetics — Hard JEE chemistry MCQ
Match the compounds in LIST-I with the observations in LIST-II, and choose the correct option.
LIST-I
(I) Aniline
(II) $o$-Cresol
(III) Cysteine
(IV) Caprolactam
LIST-II
(P) Sodium fusion extract of the compound on boiling with $\mathrm{FeSO}_{4}$, followed by acidification with conc. $\mathrm{H}_{2} \mathrm{SO}_{4}$, gives Prussian blue color.
(Q) Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(R) Addition of the compound to a saturated solution of $\mathrm{NaHCO}_{3}$ results in effervescence.
(S) The compound reacts with bromine water to give a white precipitate.
(T) Treating the compound with neutral $\mathrm{FeCl}_{3}$ solution produces violet color.
- A. $\mathrm{I} \rightarrow \mathrm{P}, \mathrm{Q}$; II $\rightarrow \mathrm{S}$; III $\rightarrow \mathrm{Q}$, R; IV $\rightarrow \mathrm{P}$
- B. $\mathrm{I} \rightarrow \mathrm{P}$; II $\rightarrow \mathrm{R}, \mathrm{S}$; III $\rightarrow \mathrm{R}$; IV $\rightarrow \mathrm{Q}, \mathrm{S}$
- C. $\mathrm{I} \rightarrow \mathrm{Q}, \mathrm{S}$; II $\rightarrow \mathrm{P}, \mathrm{T}$; III $\rightarrow \mathrm{P}$; IV $\rightarrow \mathrm{S}$
- D. $\mathrm{I} \rightarrow \mathrm{P}, \mathrm{S}$; II $\rightarrow \mathrm{T}$; III $\rightarrow \mathrm{Q}, \mathrm{R}$; IV $\rightarrow \mathrm{P}$
Solution
The correct option is **D**.